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Ideal gas: entropy change for, 159-161 fugacity of, 369-375 heat capacity of, 118-122,635 internal energy and enthalpy changes for, 67-68, 191, 198-199 property changes of mixing, 419 property relations, 191, 198-199,219 reaction equilibrium, 465 and residual property, 198-199 temperature scale, 65 Ideal-gas mixture, 120,364-368 Ideal-gas state, 64-65, 118-122, 191 Ideal solution, 384-386 chemical-reaction equilibrium, 464,466 and excess property, 386,390 properties of, 384-386 property changes of mixing for, 419-420 and Raoult's law, 327 Ideal work, 169-173,591 Immiscible systems, 553-555 Incompressible fluid, 62, 191, 194-195 Intensive property, 3,21 Intensive state, 26 Intermolecular forces, 602-608 direct electrostatic, 603-604 dispersion, 605-607 induction, 606-608 quasichemical, 616-617 Internal-combustion engine, 281-288 Internal energy, 18-19,43 differential expression for, 187-1 88, 194 of ideal gas, 67-72 microscopic view, 611-6 13 International Temperature Scale, 5 Interpolation, 662-664 Inversion curve, 249 Ionization potential (first), 606 Irreversibility, 29-30, 173-174, 239,241-244 and entropy change, 161-165, 173 Isentropic process, 159-160,212-214, 242-244,249,255-258 Isobaric process, 70, 72-73 Isothermal compressibility, 62-63, 191-192 Isothermal process, 70, 72-73 Jet engine, 289-290 Joule/Thomson coefficient, 247-248 Joule/Thomson expansion (see Throttling process) K-value for VLE, 339-346,5 13-516, 526-528,530-531 Kinetic energy, 9-10,22-23,43-44,48, 241,249 Langmuir isotherm, 569-575,579-580 Latent heat, 123-125,207-208 Riedel equation for, 125 Watson correlation for, 125 LewisrRandall rule, 385-386 and Henry's law, 404 and Raoult's law, 327 Liquefaction, 304-309 Liquidlliquid equilibrium (LLE), 541-549 Liquidlvapor equilibrium (see Vaporlliquid equilibrium) Liquids: fugacity of, 370-373 generalized density correlation, 103-104 heat capacity for, 120, 636 incompressible, 62, 191, 194-195 property changes of, 62-63, 191 P VT behavior of, 86-87,93-95 standard state for, 127 Lost work, 173-176,590-591 Mach number, 238 ~ a ~ l e 95,339,511,640-641 @, Margules equation, 408,416 Mass balance, 42-43 ~ a t h c a d @95,339,511,640-641 , Maximum velocity in flow, 239-240 Maxwell's equations, 189 MCPH, 123,199,639-640 MCPS, 161, 199,639-640 MDCPH, 132,461 Mixing process: entropy change, 367,420,424-426 Gibbs-energy change, 420,424-426 heat effect of, 366-367,420438 in ideal gas and ideal solution, 420,421 property changes, 420 Mixing rule, 378,521-522, 528-530 Molar mass, table of values for, 632-633 Molecular basis for mixture behavior, 622-626 Molecular simulation of VLE, 626-627 Molecular weight (see Molar mass) Mollier diagram, 196-197 for steam (see back endpapers) Momentum principle, 235.

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Newton's method, 490,514,714717 Newton's second law, 3 4 9 - 1 0 , 2 3 5 Nozzle, 241-245 Open system, 20,42 Osmotic equilibrium, 580-583 Osmotic pressure, 580-583 Otto cycle, 281-283 Partial pressure, 365-366, 374 Partial property, 355-365 excess, 387 graphical interpretation, 360-363 for an ideal solution, 384-385 relations among, 357-359 Partially miscible system, 541-555 Partition function, 612-613 PengIRobinson equation, 93-95 Phase, 27,58-61 Phase change, 59-61,210 Phase diagrams: binary VLE, 317-326,330-332,529, 535 binary system, limited miscibility, 542, 537-538,550-552,554 Phase diagrams: for a pure species, 59-61 Phase equilibrium, 314-346,400-415, 507-583 criteria for, 354355, 370, 374,556 (See also Adsorption equilibrium; Liquidliquid equilibrium; Osmotic equilibrium; Solidliquid equilibrium; Solidlvapor equilibrium; Vaporlliquid equilibrium; Vaporlliquidliquid equilibrium) Phase rule, 26-28, 315-316,481-484 for adsorption equilibrium, 567 PHIB, 382,641 Polytropic process, 72-73 Potential energy: gravitational, 10-1 1,22-23,41,269 intermolecular, 602 Potential function (pair), 602-611 Lennard-Jones, 603-604 2nd virial coefficient from, 608-611 square-well, 608-609 Power-plant cycle, 269-281 Rankine, 271-275 regenerative, 275-281 analysis of, 591-596 Poynting factor: for liquid-phase fugacity, 37 1 for solid-phase fugacity, 562, 565 Pressure, 6-8 critical, 58-59 effective, for H2, 97 ), interaction (PC,, 382 table of values for, 632-633 partial, 365-366, 374 pseudocritical, 223 reduced, 90 Pressurelcomposition (Pxy) diagram, 318-319,324,328-329,528,535 Pressurelenthalpy ( P H) diagram, 211, 705-706 Pressureltemperature ( P T ) diagram, 59, 61, 320-321 Pressure/volume ( P V) diagram, 59-60, 519 Process: adiabatic, 71-72, 162-163 constant-pressure, 70,73 constant-volume, 7 1,73 isentropic, 159,212-213,242-243,245, 255-258 isothermal, 70, 72 polytropic, 72-73 thermodynamic analysis of, 590-599 throttling, 245-249 Property: critical, 58-61 table of values, 632-633 from equation of state, 202-206 excess (see Excess property) extensive and intensive, 3,21 generalized correlations, 95-105, 215-224, 380-384,646-661 of ideal-gas mixture, 120, 365-368 of ideal solution, 384386 partial (see Partial property) reduced, 90, 103,223 residual (see Residual property) of single-phase system, 186-196 of two-phase system, 207-208 (See also Thermodynamic properties) Property change of mixing, 420 and excess property, 420-422 for ideal gas and ideal solution, 420 observed behavior, 424-425.

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